Synthesis, Spectroscopic, And Magnetic Properties Of Some Transition Metal Complexes With 4-[(E)-{(2e)-[(3e)-3-(Hydroxyimino)Butan-2-Ylidene]Hydrazinylidene}Methyl]Phenol
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Abstract
Complexes of diacetylmonoximehydrazide-4-hydroxybenzaldehyde (HDMHpHB) [IUPAC name: 4-[(E)-{(2E)-[(3E)-3-(hydroxyimino)butan-2-ylidene]hydrazinylidene}methyl]phenol] have been synthesized and characterized by elemental analyses, molar conductance, spectral (IR, visible, and NMR), and magnetic moment measurements. These complexes are Fe(II), Mn(II), Pd(II), Co(II), Ni(II), Cu(II), Zn(II), Hg(II), and Cd(II). Infrared spectra reveal that the ligand exhibits bidentate behavior. For the complexes [Fe(DMHpHB)2], [Mn(DMHpHB)2], [Ni(DMHpHB)2], and [Cu(DMHpHB)2] are high spin octahedral geometry, a square-planar structure is recommended for [Pd(DMHpHB)2] complex and tetrahedral geometries for [Cd(DMHpHB)2], [Hg(DMHpHB)2], and [Zn(DMHpHB)2] complexes.
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References
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